Zirconium(IV) chloride anhydrous

R1,978.88

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SKU: ZA.003.571 Category:

Description

for synthesis

Synonyms: Zirconium(IV) chloride, Zirconium tetrachloride
Empirical Formula (Hill Notation): Cl4Zr

General description

Zirconium(IV) chloride is a Lewis acid catalyst, widely used in organic synthesis for the preparation of useful key intermediates. Since it is a stable and environmentally friendly catalyst used in various chemical reactions such as carbon-carbon bond formation reactions, reduction reactions, protection, and deprotection reactions.

Application

Zirconium(IV) chloride can be used as a catalyst to synthesize:

  • β-amino alcohols by ring-opening of epoxides with aromatic amines.
  • β-amino analogs via conjugate addition of aliphatic amines to α,β-unsaturated ester, nitriles, and ketones.
  • 1,3,4-oxadiazole derivatives by cyclodehydration of 1,2-diacylhydrazines.
  • 3,4-Dihydropyrimidinone derivatives via Biginelli condensation reaction of aromatic aldehyde, β-ketoester, and urea.

Analysis Note

Assay (argentometric): ≥ 98.0 %
Hafnium (Hf): ≤ 40 ppm
Identity (ICP-OES): passes test

PROPERTIES

vapor pressure

1.3 hPa ( 190 °C)

Pack Size

250 g

form

crystals

potency

1688 mg/kg LD50, oral (Rat)

pH

<1 (20 °C in H2O, saturated aqueous solution)

mp

437 °C

density

2.80 g/cm3 at 15 °C

bulk density

1200 kg/m3

storage temp.

2-30°C

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